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Updated: Jun 16, 2025

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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表面乌尔曼聚合物的实时成像揭示了亚原子的抑制作用

Dominik Dettmann1,2, Mirco Panighel3, Navathej Preetha Genesh1

  • 1Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique Department, 1650 Boulevard Lionel-Boulet, Varennes, J3X 1P7 Québec, Canada.

Journal of the American Chemical Society
|August 21, 2024
PubMed
概括

高速扫描道显微镜捕获了乌尔曼聚合的动态,揭示了中间有机金属阶段,抑制了铜表面的碳纳米材料生长.

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Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

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Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
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