:在玻酸玻璃上升转换可见辐射的玻璃
Harpreet Singh1, Devinder Singh2, Supreet Pal Singh3
1Department of Physics, Punjabi University Patiala, (147002), Punjab, India.
Journal of fluorescence
|August 21, 2024
概括
与稀土元素合的鉛酸玻璃具有增强的向上转换特性. 这些玻璃显示了作为高效主机的潜力,用于上转换过程,在光学材料中的应用.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 频谱学是一种光谱学.
背景情况:
- 鉛酸玻璃因其物理,結構和光學特性而受到調查.
- 研究了氧化 (PbO) 作为前者或修饰物的作用,以及组成变化.
研究的目的:
- 为了合成和表征,,,酸玻璃.
- 为了研究氧化度对玻璃性能的影响.
- 为了研究稀土合玻璃的向上转换特性.
主要方法:
- 融化火技术用于玻璃合成.
- 阿基米德的密度测量原理.
- 射线衍射 (XRD) 和富里埃变换红外光谱 (FTIR) 用于结构分析.
- 紫外线-Vis吸收光谱法用于光学特性.
- 紫外-Vis-NIR光谱学用于上转换研究.
主要成果:
- 密度从3.13增加到4.51g/cm3随着PbO度的增加.
- XRD证实了眼镜的非晶体性质.
- FTIR确定了包括PbO,BO3和BO4在内的结构单位.
- 间接带间隙从4.80 eV增加到4.90 eV.
- 稀土合玻璃在980nm激发时呈现上转换发光,Er3+,Nd3+和Tm3+的特定排放峰值.
结论:
- 鉛酸玻璃具有可調的物理和光學特性,含有不同的PbO.
- 这些玻璃是稀土离子的有效宿主,促进高效的上转换发光.
- 这些材料在需要上转换现象的应用中显示出前途.
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