通过氧气空隙调节的P'2/P3混合层阴极材料实现超级循环性囊细胞
Chenxiang Li1,2, Meng Li1,2, Guozhuang Liu3
1GRINM (Guangdong) Research Institute for Advanced Materials and Technology, Foshan, Guangdong 528051, P. R. China.
ACS applied materials & interfaces
|August 22, 2024
概括
这项研究引入了用于离子电池的新型P2/P3混合相氧化阴极,增强稳定性和离子扩散,以获得卓越的循环和性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 层层的P2型氧化是离子电池的经济有效的阴极.
- 挑战包括实用能力低,由于收费/空缺订单,价格能力差.
研究的目的:
- 设计一个分层的P'2/P3混合相阴极,增强结构和热稳定性.
- 改进离子扩散动力学,以提高电池性能.
主要方法:
- 通过引入氧气空缺,合成了一个P'2/P3混合相Na0.8-Mn0.675Ni0.225Li0.1O2-阴极.
- 在半电池和全电池配置中,用硬碳阳极评估材料性能.
主要成果:
- 混合阴极表现出更好的结构和热稳定性以及更快的Na-ion扩散.
- 半细胞试验显示,在12mA/g时保持101mAh/g容量,在120mA/g500次循环后保持92.25%容量.
- 一个0.5Ah袋式电池在2600个循环后在36mA/g时保持了95.2%的容量.
结论:
- 混合相 P2/P3 阴极显示出高性能离子电池的巨大潜力.
- 引入氧气空缺是一个有效的策略,以增强分层阴极材料.
- 这项研究为开发更优质可循环的分层阴极材料铺平了道路.
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