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相关概念视频

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
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Hydroboration-Oxidation of Alkenes03:08

Hydroboration-Oxidation of Alkenes

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In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
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相关实验视频

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Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
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通过阳离子诱导的分子激活和吸附增强furfural的电催化化

Zhongcheng Xia1,2, Leitao Xu1, Chongyang Ma1

  • 1State Key Laboratory of Chem/Bio-Sensing and Chemometrics, Provincial Hunan Key Laboratory for Graphene Materials and Devices, College of Chemistry and Chemical Engineering, the National Supercomputer Centers in Changsha, Hunan University, Changsha 410082, P. R. China.

Journal of the American Chemical Society
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概括

阳离子显著影响furfural (FF) 到furfuryl酒精的电催化化. 双碳酸盐增强FF吸附和激活,导致更快的动力学,而酸盐导致反应缓慢和进化.

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科学领域:

  • 绿色化学
  • 电催化
  • 表面科学

背景情况:

  • 电催化化 (ECH) 的furfural (FF) 到furfuryl酒精是一种可持续的生产方法.
  • 了解离子效应对于优化FF ECH至关重要.

研究的目的:

  • 使用KHCO3和PBS电解质对FF ECH的阳离子影响进行研究.
  • 阐明阴离子介导分子激活和吸附的机制.

主要方法:

  • 分子动力学模拟
  • 运行同步辐射里埃变换红外光谱学
  • 在现场拉曼光谱
  • 密度函数理论计算

主要成果:

  • 双碳酸通过结促进强的FF吸附和碳基的激活.
  • 酸离子的相互作用较弱,导致酸的吸附和激活较差.
  • 与PBS相比,KHCO3电解质显示出更快的FF ECH动力学.
  • PBS电解质导致缓慢的ECH和显著的演变反应.

结论:

  • 电极微环境的离子调制是优化FF ECH的一个关键策略.
  • 基于二碳酸盐的电解质为FF电催化提供了更高的性能.