一种基于糖的新型阳离子和非阳离子Gemini表面活性剂的有效性和适用性,该表面活性剂是为甲污染的地下水整治而合成的
Yu Yao1, Yufeng Fu1, Chengwu Zhang1
1Key Laboratory of Groundwater Resources and Environment, Ministry of Education, Jilin University, Changchun 130021, China; National and Local Joint Engineering Laboratory for Petrochemical Contaminated Site Control and Remediation Technology, Jilin University, Changchun 130021, China; Jilin Provincial Key Laboratory of Water Resources and Environment, Jilin University, Changchun 130021, China.
Journal of hazardous materials
|August 22, 2024
概括
一种基于糖的新型表面活性剂通过克服传统表面活性剂的局限性,有效地修复了受污染的含水层. 这种新的表面活性剂可以在最小的环境风险下去除99%以上的乙烯 (PCE).
科学领域:
- 环境化学环境化学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 表面活性剂增强含水层修复 (SEAR) 对于去除密集非水相液体 (DNAPLs) 至关重要.
- 传统的表面活性剂面临着诸如降水,吸附损失和不良溶解等挑战,从而降低了修复效率.
- 限制包括在低温和高盐度地下水中的性能问题.
研究的目的:
- 设计和合成一种新的基于糖的阳离子和非阳离子双子座表面活性剂 (SANG),以改善SEAR.
- 通过解决沉,吸附损失和溶解问题来提高表面活性剂的性能.
- 评估SANG在从受污染的含水层中去除乙烯 (PCE) 的有效性.
主要方法:
- 一种结合葡萄糖 (非离子),硫酸 (离子) 和双链的双胞胎表面活性剂的合成.
- 在各种条件下 (低温,高盐含量) 测试SANG的稳定性和溶解性.
- 在不同类型的沙子中量化吸附损失,并评估PCE溶解和脱吸能力.
主要成果:
- 在没有降水的情况下,SANG在具有挑战性的含水层条件下表现出稳定性和溶解性.
- 达到非常低的吸附损失:在中等砂中达到0.54 mg/g,在细砂中达到0.90 mg/g.
- 与典型的表面活性剂相比,SANG在没有乳化的情况下表现出优异的PCE溶解和脱落,导致>99%的PCE去除.
结论:
- 桑格为S.E.A.R.提供了一个高效和环保的替代方案.
- 它独特的结构克服了复杂的地下水环境中的传统表面活性剂的局限性.
- 桑格显示出对像PCE这样的DNAPL有效地进行地下修复的显著前景.
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