防侵蚀屏蔽:探索侵蚀前表面腐蚀抑制剂的有效性
Zhongying Xu1, Xuewen Cao1, Pengshen Wang2
1College of Pipeline and Civil Engineering, China University of Petroleum (East China), Qingdao 266580, China.
Journal of colloid and interface science
|August 24, 2024
概括
预侵蚀显著降低了X65钢的伊米达林腐蚀抑制剂的有效性,特别是在30°的角度下. 与HEIE相比,TDEI在这些粗的表面上显示出更好的吸附和保护.
科学领域:
- 材料科学 材料科学 材料科学
- 腐蚀工程 腐蚀工程
- 表面化学 表面化学
背景情况:
- 在各种行业中,X65钢的腐蚀对各种行业构成重大挑战.
- 了解腐蚀抑制剂在粗表面的吸附行为对于有效保护至关重要.
- 伊米达佐林衍生物被广泛用作腐蚀抑制剂.
研究的目的:
- 调查HEIE和TDEI在预侵蚀X65钢上的防腐性能.
- 分析表面地形对抑制剂吸附和有效性的影响.
- 为了比较HEIE和TDEI的吸附机制和保护能力.
主要方法:
- 测量减重量,以量化腐蚀.
- 电化学技术 (例如,潜在动力极化) 来评估抑制效率.
- 分子动力学 (MD) 模拟用于研究吸附能和扩散系数.
主要成果:
- 预侵蚀,特别是在30°的角度,可显著降低腐蚀抑制效率高达11.9%.
- 与HEIE相比,TDEI显示了较低的能量带隙值和更多的负吸附能 (Eads).
- 对于腐蚀剂,TDEI的扩散系数较小,这表明吸附力更强,保护性更好.
结论:
- 侵蚀前的表面不规则阻碍了均的抑制剂吸附,降低了有效性.
- 与HEIE相比,TDEI在预侵蚀的X65钢上提供了优越的腐蚀抑制.
- 这项研究为开发更好的防护策略提供了洞察力,以改善腐蚀钢表面的保护策略.
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