通过改性飞灰稳定Pb/Zn矿山尾矿:特征,性能和机制
Xiaogang Sun1, Yingliang Zhao2,3, Yong Sun1
1College of Resources and Civil Engineering, Northeastern University, Shenyang, China.
Environmental science and pollution research international
|August 27, 2024
概括
修改后的飞灰有效地稳定了矿山尾矿中的和,大大减少了重金属的漏. 这种创新方法提高了环境保护和监管合规性.
科学领域:
- 环境科学 环境科学
- 地质化学 地质化学
- 材料科学 材料科学 材料科学
背景情况:
- 矿山尾矿中的重金属存在重大环境风险.
- (Pb) 和 (Zn) 是矿山废物中常见的污染物.
- 有效的稳定方法对于减轻环境污染至关重要.
研究的目的:
- 使用改性飞灰 (FA) 来稳定含有Pb/Zn的矿山尾矿.
- 通过修改的FA来研究Pb和Zn的吸附机制.
- 评估Na2SiO3修饰的FA (NaSi-FA) 在减少重金属漏方面的有效性.
主要方法:
- 用溶液,特别是Na2SiO3.3,修改飞灰的方法
- 批量吸附实验以确定Pb和Zn的吸附能力.
- 兰木尔等温和和伪二次运动模型.
- 分子动力学模拟以阐明离子交换机制.
- 漏试验用于评估稳定效率.
主要成果:
- NaSi-FA 呈现出显著的结构变化,增强了表面积和多孔性.
- 与未经修改的样本相比,在修改的FA中,Pb和Zn的吸附能力翻了一番.
- 吸附遵循兰格穆尔等温和和伪二次运动模型.
- 分子动力学证实了N-A-S-H凝中的Pb和Zn离子与Na+交换.
- NaSi-FA处理减少了55.2%的Pb出和35.3%的Zn出.
结论:
- NaSi-FA是稳定Pb/Zn矿山尾矿的一种高效材料.
- 增强的表面特性和离子交换机制有助于有效的重金属固定.
- 这种方法显著降低了来自矿山尾矿的重金属污染对环境的风险.
- 稳定方法证明了对重金属封装的环境法规的遵守.
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