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Updated: Jun 15, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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在Eu-MOF中对Cyclopentadienyl Cobalt进行不对称的修改,用于C2H2/CO2分离

Xiaokang Wang1, Hongyan Liu1, Meng Sun1

  • 1School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, China.

Inorganic chemistry
|August 28, 2024
PubMed
概括

一个新的金属有机框架 (MOF),UPC-119,显示出有效地将乙 (C2H2) 与二氧化碳 (CO2) 分离的希望. 这种材料具有高吸附能力和易于再生,用于低能耗的气体净化.

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Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
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