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Updated: Jun 15, 2025

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
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Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts

Published on: August 7, 2018

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通过一个多价值II-有机框架,增强Cr (VI) 的光降解,其中包含了基分子

Xin Li1, Rong-Hua Liu1, Xue-Ke Han1

  • 1Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China.

Inorganic chemistry
|August 28, 2024
PubMed
概括

一个新的二维基金属有机框架 (MOF),LCUH-120,有效地使用光线将有毒的CrVI转化为CrIII. 这种稳定的光催化剂在温和条件下在40分钟内实现了完全的减少.

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A Technical Guide for Performing Spectroscopic Measurements on Metal-Organic Frameworks10:13

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Radical Oxidation of Allylic and Benzylic Alcohols

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The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
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Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
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