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Updated: Jun 15, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

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高电友性和稳定的金属化物复合物的设计

Jing Xiang1, Huatian Shi2, Wai-Lun Man3

  • 1School of Optoelectronic Materials and Technology, Jianghan University; Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, Jianghan University, Wuhan 430056, China.

Accounts of chemical research
|August 28, 2024
PubMed
概括

研究人员开发了稳定,高度氧化的金属化物复合物,包括 (VI) 和 (VI) 种,用于研究与有机基质的反应性. 这些新型化合物为化学合成和催化提供了新的途径.

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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