来自B2O3-受限多环芳香化合物的超高温长持续发光
Yuanfei Ding1, Chenyu Yang1, Fuwei Gan1
1School of Chemistry and Chemical Engineering, Zhangjiang Institute for Advanced Study, Frontiers Science Center for Transformative Molecules, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China.
Journal of the American Chemical Society
|August 28, 2024
概括
限制在氧化晶体中的多环芳香化合物 (PAC) 即使在400°C时也表现出持久的后发光. 这一突破使得在极端环境中实现了先进的应用.
科学领域:
- 材料科学
- 光物理学
- 有机化学
背景情况:
- 由于成本和设计灵活性,有机分子和聚合物被探索为后发光材料.
- 在高温下实现长期持续的发光存在挑战,原因是三重激发状态的快速失活.
研究的目的:
- 开发能够在高温下持续发光的有机反光材料.
- 为了研究高温长时间持续发光在受限有机分子的机制.
主要方法:
- 在酸溶液中分散多环芳香化合物 (PAC).
- 干燥,化和脱水形成B2O3晶体网络.
- 在高温下限制在B2O3矩阵中的PACs的发光特性.
主要成果:
- 限制在B2O3晶体中的PAC显示长时间持久的发光度高达400°C.
- 刚性B2O3网络限制了分子运动,防止三重激子的非辐射衰变.
- 后照色可以从UV调整到NIR,通过光和热激活的延迟光响应温度和时间.
结论:
- 将PAC限制在B2O3晶体中是一种有效的策略,可以实现超高温的长时间持续发光.
- 开发的材料有望在3D温度探测,防伪和极端条件下数据加密等领域应用.
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