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边际聚合物:粘土的作用
Arnon Bentur1, Pavel Larianovsky1
1National Building Research Institute, Faculty of Civil and Environmental Engineering, Technion, Israel Institute of Technology, Haifa 3200003, Israel.
Materials (Basel, Switzerland)
|August 29, 2024
概括
聚合物中的粘土,以甲基蓝值 (MBV) 为特征,影响混凝土的水需求. 硫酸盐和聚碳酸盐 (PC) 等添加剂可以减轻这些影响,可能将微细变成有益的混凝土填充剂.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 地质化学 地质化学
背景情况:
- 在聚合物加工过程中,常常会去除粘土 (微细度<75微米).
- 边缘聚合物来源可能含有显著的粘土含量,创造了一个保留它们的激励.
- 了解粘土对水泥系统的影响对于利用这些细质材料至关重要.
研究的目的:
- 为了全面描述聚合物中的粘土成分.
- 量化粘土对混凝土的气质和机械性能的影响.
- 确定对有害的粘土影响的缓解策略.
主要方法:
- 粘土组成的特征.
- 量化粘土对混凝土性能的影响.
- 对用于中和的添加剂 (硫酸盐,聚碳酸盐 (PC),粘土减轻添加剂 (CMA)) 的评价.
- 评价微细作为功能填充剂.
主要成果:
- 由于粘土而增加的混凝土水需求可以通过含量和甲基蓝值 (MBV) 来量化.
- 硫酸盐中和低/中等的MBV效应高达150kg/m3; PC是需要更高的含量.
- 高MBV聚合物需要PC和CMA的组合.
- 经过处理的微细颗粒可以作为增强强度的填充剂,减少水泥含量.
结论:
- 粘土含量和MBV为评估它们对混凝土的影响提供了合理的基础.
- 特定的添加剂可以有效地减轻混凝土中的粘土的有害影响.
- 微细颗粒,包括粘土,可以在混凝土配方中作为有价值的功能填充剂重新使用.
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