利用木底灰来有效地从废水中去除:吸附机制和过程优化
Jae-In Lee1, Yohan Jeong2, Youn-Jun Lee3
1Institute of Agricultural Environmental Science, Hankyong National University, Anseong, 17579, Republic of Korea.
Chemosphere
|August 29, 2024
概括
木底灰通过化学吸收有效地从废水中去除. 优化条件实现了高去除,为发展中国家提供了可持续的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 水处理 处理水的方法
背景情况:
- 废水中的污染对环境和健康构成重大风险.
- 有效和可持续的吸附材料对于修复至关重要.
- 木底灰 (WBA) 是一种潜在的低成本吸附剂,来自生物质废物.
研究的目的:
- 研究木底灰 (WBA) 作为从废水中去除 (As) 的吸附剂的有效性.
- 阐明吸附机制,并优化使用WBA去除As的操作参数.
- 评估WBA作为可持续和成本有效的废水处理解决方案的潜力.
主要方法:
- 用光谱分析 (FE-SEM/EDS,BET,XRF,XRD,FT-IR,XPS) 来描述吸附前后的WBA.
- 吸附动力学和异热学研究,以确定吸附行为和能力.
- 响应表面方法 (RSM) 以优化关键操作参数 (pH,离子强度,吸附剂剂量,反应时间).
主要成果:
- 在WBA中,的最大吸附能力为121.13mg/g.
- 吸附遵循伪二阶动力学和兰迈尔异热模型,表明化学吸附和单层吸附.
- 最佳的去除条件是pH 7.11,8.37mM的离子强度,9.08g/L的WBA剂量和2.58小时的反应时间.
- 无形甲表面沉被确定为主要的去除机制.
结论:
- 木底灰是从废水中去除的高效吸附剂.
- 吸附过程由化学吸附控制,表面沉是关键机制.
- 优化的WBA应用程序为补救提供了一种具有成本效益和可持续的方法,特别是在发展中国家.
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