对质子交换膜电解器的梯度孔状输送层进行全面分析
Yang Liu1,2, Qiu Diankai1,2, Zhutian Xu1,2
1State Key Laboratory of Mechanical System and Vibration, Shanghai Jiao Tong University, Shanghai 200240, P. R. China.
ACS applied materials & interfaces
|August 30, 2024
概括
梯度多孔性多孔运输层 (PTLs) 显著提高了质子交换膜水电解器 (PEMWE) 的性能. 这项研究表明,cis梯度PTL通过优化质量转移和界面接触来提高效率,从而改善水电解.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 质子交换膜水电解器 (PEMWE) 需要高效的多孔传输层 (PTL) 来最大限度地减少质量转移损失.
- 优化 PTL 结构是提高 PEMWE 业绩和降低运营成本的关键.
研究的目的:
- 调查梯度孔径PTL对PEMWE性能的影响.
- 分析PTL结构对质量转移和界面接触的影响.
- 了解在梯度孔隙 PTL 中的双相流和运输机制.
主要方法:
- 在PEMWE中对梯度孔隙性PTL进行实验测试.
- 使用实际几何学,在PTL中对两相 (氧-水) 流量进行二维数值建模.
- 对质子,电子和催化站点运输的界面接触效应的微观分析.
主要成果:
- 一个Cis梯度孔隙性PTL在2.2A/cm2时表现出9.3%的性能提升.
- 数字模拟确定了表面张力和压力下降是氧气运输的关键驱动因素.
- 带有 cis-梯度孔隙的 PTL 下部区域的较低氧和度减少了催化剂层的氧气覆盖.
结论:
- 梯度孔径PTL为提高PEMWE性能提供了一个可行的策略.
- 了解微型运输现象对于PTL设计至关重要.
- 优化的PTL结构可以提高水电解效率和耐用性.
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