草/PLA复合材料的制备,具有优异的阻燃性,基于深度环氧化溶剂硫化
Rui Yang1, Jing Zhou2, Xiangzhen Meng2
1Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing, Jiangsu 210037, China; China Jiangsu Key Open Laboratory of Wood Processing and Wood-Based Panel Technology, Nanjing, Jiangsu 210037, China.
International journal of biological macromolecules
|September 1, 2024
概括
这项研究增强了草/PLA复合材料与硫基组的优越阻燃性和机械完整性. 这种新方法避免了传统的阻燃剂,保持了材料的强度,同时提高了安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 绿色化学 绿色化学
背景情况:
- 天然纤维/PLA复合材料在各种应用中都有很高的需求.
- 现有的阻燃方法往往会损害这些复合材料的机械性能.
- 需要有效的阻燃剂策略来保持材料的完整性.
研究的目的:
- 为草/PLA复合材料开发一种阻燃剂修改.
- 通过基于硫胺酸的深溶解剂 (SDES) 修饰,将硫基组引入纤维素中.
- 为了实现阻燃性,而不会对机械性能产生负面影响.
主要方法:
- 修改草纤维,使用基于硫酸的深性溶剂 (SDES).
- 将修改的草纤维纳入聚乳酸 (PLA) 中,以形成DS/PLA复合材料.
- 评价阻燃性,热稳定性和机械性能.
主要成果:
- 修改后的草/PLA (DS/PLA) 复合材料表现出极好的阻燃性.
- 限制氧气指数 (LOI) 达到36.53%.
- 热稳定性显著改善,剩余碳从7.8%增加到38.4%.
- 拉伸模量增加了69.5%,显示出增强的机械性能.
- 制备方法简单,经济,高效.
结论:
- 使用SDES将硫基组引入草纤维是PLA复合材料的有效阻燃策略.
- 这种方法可以提高阻燃性和热稳定性,而不会损害机械性能.
- 这项研究为天然纤维/塑料复合材料的阻燃修饰提供了宝贵的参考.
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