一种基于生物的玻璃仪:通过动态共价键交换诱导的自我愈合,形状记忆和可回收性
Hao-Hao Liu1, Yan Ma2, Yong-Hong Zhou1,2
1College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, Jiangsu Province, China.
ACS omega
|September 2, 2024
概括
这项研究引入了从植物油中提取的全新的,完全基于生物的玻璃制剂. 这些可持续的聚合物在不需要催化剂的情况下表现出增强的机械强度和自我愈合特性,为先进材料铺平了道路.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续化学 可持续化学
背景情况:
- 基于植物油的玻璃制品在先进材料中提供了可持续的替代品.
- 目前的局限性包括机械性能差和催化剂依赖.
- 可再生卡达是生物基聚合物的有希望的原料.
研究的目的:
- 从卡达诺醇开发一种无催化剂,完全基于生物的玻璃化物.
- 为了增强机械性能和引入自我愈合能力.
- 探索酸作为治愈剂的潜力.
主要方法:
- 卡尔达诺被功能化,以创建环氧卡尔达诺糖基乙烯 (ECGE).
- 使用酸 (CA) 来形成玻璃体,ECGE被治愈.
- 描述的重点是机械强度,自我愈合和可回收性.
主要成果:
- 在没有催化剂的情况下,成功生产了完全基于生物的ECGE-CA玻璃剂.
- 这些玻璃体具有很高的机械强度和显著的自我愈合特性.
- 在CA中存在基团,促进了键和网络重组.
结论:
- 从卡达诺和酸制成的无催化剂,生物基的玻璃化物是可行的.
- 这些材料表现出卓越的机械性能和自我愈合能力.
- 开发的玻璃材料对可回收的粘合剂和可修复的材料具有前景.
相关概念视频
Polymers
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...
Noncovalent Attractions in Biomolecules
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Noncovalent Attractions in Biomolecules
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Polymers
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...
Bioplastics
Bioplastics derived from microbial processes present a sustainable alternative to conventional petroleum-based plastics. Among these, polyhydroxyalkanoates (PHAs), particularly polyhydroxybutyrates (PHBs), have emerged as prominent candidates due to their biodegradability and biocompatibility. These polymers are synthesized by a variety of bacteria, such as Cupriavidus necator and Pseudomonas putida, which naturally accumulate PHAs as intracellular carbon and energy reserves, especially under...
Microbial Bioremediation of Plastics
Polyethylene terephthalate (PET) is a synthetic polymer widely utilized in the packaging industry, particularly for bottles and containers. Due to its chemical stability and durability, PET accumulates in the environment, contributing significantly to plastic pollution. It comprises repeating units of terephthalic acid and ethylene glycol, resulting in a semi-crystalline structure that is resistant to natural degradation processes.A notable breakthrough in plastic biodegradation came with the...


