化物MXenes中的可调性磁性:原子层堆叠的后果
Himangshu Sekhar Sarmah1, Subhradip Ghosh2
1Department of Physics, Indian Institute of Technology Guwahati, Guwahati-781039, Assam, India. shimangshu@iitg.ac.in.
Nanoscale
|September 2, 2024
概括
堆叠模式显著影响化物MXenes (M2NT2) 的电子和磁性. 这一发现为通过调整材料结构来设计先进的磁器件提供了新的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 量子化学 是一个量子化学.
背景情况:
- 像MXenes这样的二维材料由于其构成灵活性而具有独特的特性.
- 化物MXenes的探索比碳化物对应物少.
- 结构方面及其对MXene特性的影响是新兴的研究领域.
研究的目的:
- 研究堆叠模式对化物MXenes电子和磁性特性的影响.
- 探索M2NT2化合物的磁力中的结构属性关系.
- 确定磁性设备中的潜在应用.
主要方法:
- 基于密度函数理论 (DFT) 的计算.
- 分析基本状态和有限温度的磁性特性.
- 检查电子结构和局部对称性.
主要成果:
- 堆叠模式大大影响了M2NT2 MXenes (M = Sc, Ti, V, Cr, Mn; T = O, F) 的磁性特性.
- 电子接地状态可以通过堆叠模式修改来调整.
- 性与局部对称性,结构不均性和电子结构有关.
结论:
- 堆叠模式工程是一个可行的策略来控制化物MXenes的电子和磁性特性.
- 这些发现为新的磁器件应用铺平了道路.
- 了解结构属性关系是化物MXene开发的关键.
更多相关视频
07:42Optimizing Magnetic Force Microscopy Resolution and Sensitivity to Visualize Nanoscale Magnetic Domains
Published on: July 20, 2022
2.7K
06:49Radio Frequency Magnetron Sputtering of GdBa2Cu3O7âˆ'ÃŽ ´/ La0.67Sr0.33MnO3 Quasi-bilayer Films on SrTiO3 STO Single-crystal Substrates
Published on: April 12, 2019
7.6K
相关概念视频
Atomic Nuclei: Magnetic Resonance
639
The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
639
Atomic Nuclei: Nuclear Relaxation Processes
632
In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis, the precessing magnetic moments are randomly oriented around the z-axis.
632
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Diamagnetism
2.4K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.4K
Atomic Nuclei: Nuclear Spin State Overview
902
NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of...
902
Paramagnetism
2.5K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.5K
