一个两级无氧EGSB反应器系统的长期性能和活动研究,该系统处理复杂和有毒的工业废水
Ruben Garcia-Tirado1, Emma Fernandez-Crespo1, Xavier Font2
1Department of Mechanical Engineering and Construction, Jaume I University, Castellón de la Plana, Spain.
概括
这项研究表明,两级扩展颗粒式污泥床 (EGSB) 反应堆可以处理复杂的石化废水. 长期运行需要定期重新排水,因为慢性毒性会影响无氧生物质.
科学领域:
- 环境工程 环境工程
- 生物技术是生物技术.
- 废水处理 废水处理
背景情况:
- 无氧处理是有效的工业废水,生产生物气.
- 石化废水的复杂性和毒性限制无氧反应堆的实施.
- 扩展颗粒床 (EGSB) 反应器为挑战废水提供高效率.
研究的目的:
- 研究石油化工废水处理的两阶段EGSB系统.
- 评估COD清除和生物气生产的操作参数 (OLR,HRT).
- 评估长期运行的生物质活动和废水毒性.
主要方法:
- 经营的板和试点规模的两级EGSB反应堆.
- 研究了有机载荷率 (OLR) 和液压保留时间 (HRT) 的影响.
- 监控的化学氧气需求 (COD) 清除,生物气产量,组成,硫化物 (H2S),特定甲原性活性 (SMA) 和毒性.
主要成果:
- 在试点规模上,达到了24小时的最佳总HRT,达到56.30%的COD和31.68%的SO4^2-去除.
- 平均生物气产量为93.47 NL/天,其中67.01%为CH4和5210.11 ppmv H2S.
- 慢性毒性在600天后降低了SMA的数量,需要重新排卵.
结论:
- 两级EGSB反应堆可用于处理复杂的石化废水 (0.97-1.74 gCOD/L/day OLR).
- 废水对无氧生物质具有抑制性和毒性作用.
- 由于慢性毒性,定期重新排水对于持续的长期无氧治疗至关重要.
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