"呼吸"Bi/N-CNSs准阵列结构的规模构建,用于离子电池的等级Bi分布
Jian Hui Jia1, Jie Bai1, Chun Cheng Yang1
1Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering, Jilin University, Changchun 130022, China.
Nano letters
|September 4, 2024
概括
研究人员开发了一种用于离子电池 (SIB) 的新型/N-化碳纳米板复合材料. 这种材料提供了特殊的循环寿命和性能,解决了SIB发展中的关键挑战.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 由于其安全性和成本效益,是离子电池的有吸引力的替代品.
- 目前的SIB开发面临的挑战是复杂的电极材料合成和低于最佳的储存能力.
- 先进的电极材料对于提高SIB性能和商业可行性至关重要.
研究的目的:
- 为了合成一种新的/N-化碳纳米片 (Bi/N-CNSs) 复合物,以改善的储存.
- 在SIB中研究Bi/N-CNSs复合物的电化学性能.
- 为先进的电池材料展示一种可扩展和多功能合成方法.
主要方法:
- 制备一种具有准阵列结构和等级分布的石/N-合碳纳米片 (Bi/N-CNSs) 复合物.
- 作为SIBs的电极材料的Bi/N-CNSs复合物的电化学表征.
- 评估循环稳定性,速度能力和低温性能.
主要成果:
- 这种Bi/N-CNSs复合体的超长寿命为26,000个周期,在5 A g-1.1时.
- 高速能力被证明是91.5%的容量保留在100Ag-1.1.
- 在-40°C (161 mAh g-1 在5 A g-1 时) 和可扩展的合成方法 (14.53 g 批量产量) 实现了出色的性能.
结论:
- 开发的Bi/N-CNSs复合材料提供了卓越的储能性能,解决了当前SIB技术的关键局限性.
- 准阵列结构和层次的斯木分布是增强电化学性能的关键.
- 可扩展和可适应的合成方法对金属基电池材料的更广泛开发具有前景.
相关概念视频
Ionic Crystal Structures
14.2K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.2K
Trends in Lattice Energy: Ion Size and Charge
23.8K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
23.8K
Ionic Bonding and Electron Transfer
41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.3K
Batteries and Fuel Cells
27.2K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.2K


