在有组织的流体流动条件下,从聚合物表面释放污染物
Markéta Kadlečková1,2, Karolína Kocourková1, Filip Mikulka1
1Department of Physics and Materials Engineering, Faculty of Technology, Tomas Bata University in Zlín, Vavrečkova 5669, 760 01 Zlín, Czech Republic.
Water research X
|September 5, 2024
概括
聚合物的温度梯度加快了污染物释放到水中的速度. 与稳定状态条件相比,对流动流动有显著的影响,影响储存和分配系统中的水安全.
科学领域:
- 材料科学 材料科学 材料科学
- 环境科学 环境科学
- 聚合物化学 聚合物化学
背景情况:
- 在水系统中使用聚合物需要对材料表面的污染进行监测.
- 当前的测试标准通常使用恒定温度,不反映不同的环境条件.
- 温度梯度可以诱导流动,可能增加污染物出.
研究的目的:
- 调查温度梯度和由此产生的流量对聚乙烯污染物释放的影响.
- 为了在稳定状态,混合和对流流动条件下比较污染物释放.
主要方法:
- 使用聚乙烯作为聚合物模型.
- 模拟稳定状态和有组织的流量条件.
- 使用表面张力,UV-Vis光谱学,FTIR,SEM和元素分析分析了水浸出物和聚合物表面.
主要成果:
- 由温度梯度驱动的对流流量显著增加了污染物的释放.
- 在对流流和稳定状态/混合条件之间,释放速率显著不同.
- 分析技术证实了聚合物表面和液成分的变化.
结论:
- 温度梯度是影响水系统中聚合物污染物漏的关键因素.
- 电流流动条件加快了不良物质的释放.
- 标准测试协议可能会低估在现实世界,非热带环境中的泄漏风险.
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