所有气候离子电池的稳定性和快速充电性正极材料
Hao Zhang1, Qiubo Li1, Xinyue Xu1
1Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090, PR China.
Journal of colloid and interface science
|September 5, 2024
概括
一种新的酸 (NaTiP2O7) 涂层增强了离子电池的Na3.12Fe2.44(P2O7) 2阴极,提高了长时间,高性能储能的速率能力和空气稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (SIB) 对电网规模的储能充满希望.
- Na3.12Fe2.44(P2O7) 2 (NFPO) 阴极提供了成本效益和结构稳固性.
- NFPO的性能受到缓慢的离子动力学和差的接口/空气稳定性的阻碍.
研究的目的:
- 为了提高SIB的NFPO阴极材料的电化学性能和稳定性.
- 为了解决N-ion迁移和接口稳定性的局限性.
- 为改进的阴极材料开发可扩展的涂层方法.
主要方法:
- 使用液相涂层方法合成了涂有NaTiP2O7 (NTPO) 的NFPO (NFPO-NTPO).
- 进行了NTPO涂层含量的优化.
- 电化学性能通过各种C率,循环数和温度 (-40至60°C) 进行评估.
- 在28天的时间内评估了空气稳定性.
主要成果:
- NFPO-NTPO-4%阴极在0.1C时实现了108.4mAhg-1的可逆特异容量.
- 在10C (相对于0.1C) 时观察到高容量保留率为88.39%.
- 在3000个循环 (92.66%的保留) 和5000个循环20C (88.89%的保留) 证明了特殊的循环稳定性.
- 材料在暴露于空气28天后,在广泛的温度范围内保持性能.
结论:
- NTPO涂层有效地改善了NFPO的Na-ion迁移动力学和接口稳定性.
- 对于SIBs来说,NFPO-NTPO证明了优越的速率能力,长期循环稳定性和空气稳定性.
- 这种增强的阴极材料显示出在离子电池中实际应用的潜力,包括要求苛刻的温度条件.
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