多孔有机聚合物作为高性能性膜水电解的离子体
Sandra Rico-Martínez1,2, Hyeon Keun Cho2, Chuan Hu2,3
1IU CINQUIMA, Department of Inorganic Chemistry, Faculty of Science, University of Valladolid, 47011, Valladolid, Spain.
ChemSusChem
|September 5, 2024
概括
研究人员开发了新的多孔有机聚合物 (POPs) 用于离子交换膜水电解器 (AEMWEs). 这些POP为可持续的生产提供了高性能和耐用性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 可持续能源 可持续能源
背景情况:
- 离子交换膜水电解器 (AEMWE) 对于可持续的生产至关重要.
- 目前的AEMWEs需要提高性能和耐用性才能得到广泛采用.
研究的目的:
- 为AEMWEs开发新的多孔有机聚合物 (POPs) 作为固体离子体.
- 评估这些新型的POP的电化学特性和性稳定性.
主要方法:
- 通过通过电友芳香替代与芳香单体反应4 - 甲基二来合成POPs.
- 使用合成的POP离子体制造和测试AEMWE.
- 在性条件下特征电化学性能和耐用性.
主要成果:
- 在1M KOH中,在2.0V和80°C时达到13.4A/cm2的记录电流密度.
- 经过500多小时的长期耐用性证明,电压衰减率为120μV/h,0.5A/cm2.
- 呈现出卓越的电化学性能和显著的性稳定性.
结论:
- 新的POPs代表了AEMWE的固态离子体的重大进步.
- 这项研究为设计用于能源转换设备的强大,高性能离子体提供了一条途径.
- 低成本的合成方法为可扩展和经济的生产提供了潜力.
相关概念视频
Ion Exchange
565
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
565
Potentiometry: Membrane Electrodes
499
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
499
Aqueous Solutions and Heats of Hydration
14.6K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.6K
Anionic Chain-Growth Polymerization: Overview
2.1K
The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
2.1K
Intermolecular Forces
58.0K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
58.0K


