用于离子电池的空气稳定的分层氧化物阴极的K-丰富的螺旋接口
Xiaowei Liu1, Yaqing Guo2, Qian Zhang3
1State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China.
Advanced materials (Deerfield Beach, Fla.)
|September 9, 2024
概括
过渡金属层氧化物在水中浸泡后变得空气稳定. 一个新的螺旋层形成,保护材料并保持离子储存的电化学性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 固态化学 固态化学
背景情况:
- 含的过渡金属层氧化物 (KxTmO2) 为离子储存提供高能量密度.
- 它们的二维分层结构导致严重的湿透性能和空气敏感性,损害稳定性并增加成本.
研究的目的:
- 研究一种用于提高P3型KxTmO2阴极材料的空气稳定性的新方法.
- 了解水浸浸引起的表面转变机制.
主要方法:
- 在水中浸泡后对P3型KxTmO2进行实验调查.
- 密度函数理论 (DFT) 计算来分析表面相位.
- 对暴露在空气中的样品进行电化学性能测试.
主要成果:
- 令人惊的是,浸泡在水中会在P3型KxTmO2上诱导一种超薄的,富含的旋转相包裹层.
- 这种螺旋层显著降低了表面与空气的反应性,从而保持了结构完整性.
- 经过水处理的材料保持了出色的电化学性能,在暴露在空气中后保持99.15%的容量.
结论:
- 在现场表面相位转换为保护性旋转层有效地提高了P3型KxTmO2的空气稳定性.
- 这种由水诱导的机制适用于其他KxTmO2材料,为K+储存提供了成本有效的策略.
- 这些发现挑战了使用水来提高空气稳定性的传统方法.
相关概念视频
Alkali Metals
19.1K
Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
Table 1: Properties of the alkali metals
19.1K
Electron Configuration of Multielectron Atoms
39.6K
The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
39.6K
Electrolysis
26.2K
In a galvanic cell, the electrical work is done by a redox system on its surroundings as electrons produced by the spontaneous redox reactions are transferred through an external circuit. Alternatively, an external circuit does work on a redox system by imposing a voltage sufficient to drive an otherwise nonspontaneous reaction in a process known as electrolysis. For instance, recharging a battery involves the use of an external power source to drive the spontaneous (discharge) cell reaction in...
26.2K
Ionic Bonding and Electron Transfer
41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
41.3K


