对AECl2-NdCl3 (AE = Sr,Ba) 系统的实验调查和热力学建模评估
D C Alders1, D J Cette1, R J M Konings1
1Delft University of Technology, Faculty of Applied Sciences, Radiation Science & Technology Department, Mekelweg 15, 2629 JB Delft, The Netherlands. a.l.smith@tudelft.nl.
Physical chemistry chemical physics : PCCP
|September 9, 2024
概括
这项研究研究了化-化和化-化盐系统的热力学特性. 研究人员确定了中间盐和量化了固体溶解度,这对于材料科学应用至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 热力学是一种热力学.
- 固态化学 固态化学
背景情况:
- 了解二元盐系统的热力学和热物理性质对于开发先进材料至关重要.
- 基于化 (NdCl3) 的系统对各种工业应用具有兴趣.
研究的目的:
- 为了研究AECl2-NdCl3 (AE = Sr,Ba) 双盐系统的热力学和热物理性质.
- 在这些系统中识别和描述中间化合物和固体溶液.
- 使用CALPHAD方法进行热力学评估.
主要方法:
- 实验调查包括X射线衍射 (XRD) 用于结构分析.
- 火实验和差分扫描热量计 (DSC) 进行相位平衡.
- 使用CALPHAD方法与特定的吉布斯能量模型进行热力学建模.
主要成果:
- 单个中间盐的鉴定:Sr9Nd5Cl33和Ba3Nd2Cl12.
- 证实了 NdCl3 在 SrCl2 和 BaCl2.2 中的互溶性.
- 基于实验数据,对二进制系统进行了成功的热力学评估.
结论:
- 该研究提供了对SrCl2-NdCl3和BaCl2-NdCl3系统的全面热力学理解.
- 描述的中间阶段和固体溶液是预测阶段行为的关键.
- 与实验数据相结合的CALPHAD方法提供了一种可靠的热力学评估方法.
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