用不同粘度的油膨胀的聚合物表面的湿脊的相隔动态
Zhuoyun Cai1, Rodrique G M Badr2, Lukas Hauer3
1Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40506, USA.
Soft matter
|September 9, 2024
概括
膨胀油的粘度显著影响软弹性体上的湿脊的相分离. 低粘度油最初分离得更快,而高粘度油在后期发展得更快.
科学领域:
- 软物质物理学 软物质物理学
- 表面科学是一门科学.
- 材料科学是一种材料科学.
背景情况:
- 软表面上的水滴由于表面张力而形成湿.
- 毛细体可以在胀的弹性体上诱导这些湿脊的相位分离.
研究的目的:
- 为了研究用油膨胀的弹性体上的糖醇滴中相位分离的动力学.
- 为了确定膨胀油粘度对相隔特性的影响.
主要方法:
- 使用共聚焦显微镜观察相位分离动态.
- 在弹性体上使用糖滴,其胀与不同粘度的油.
- 分析了石油分离的大小,速度和生长模式.
主要成果:
- 膨胀油粘度是油分离大小和速度的一个关键因素.
- 低粘度油在早期显示出更大,更快的分离.
- 晚期分离的增长速度取决于粘度和膨胀率,根据扩散模型.
- 更高粘度的油在晚期湿中表现出更快的增长.
- 分离的油相区域保持了一致的,几何上相似的形状.
结论:
- 油的粘度决定了膨胀的弹性体中的相隔行为.
- 了解这些动力学可以告知滴水表面相互作用的控制,如扩散和粘附.
- 观察到的相位分离为控制表面特性提供了洞察力.
相关概念视频
The Colloidal State
The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the concentration...


