一个工程有孔的球形碳阴极,用于高能离子电容器
Youyu Zhu1, Xiaofang Tang1, Ranran Ding2
1College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, Shanxi, China.
Langmuir : the ACS journal of surfaces and colloids
|September 9, 2024
概括
研究人员从湿酸中开发了球形多孔碳 (SPC) 用于离子混合电容器 (SIC). 这些SPC阴极提供了高容量和稳定性,改善了用于储能应用的SIC性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子混合电容器 (SIC) 对能源和电力平衡具有前景.
- 高容量阴极对于推进SIC技术至关重要.
- 目前的局限性阻碍了SIC的全部潜力.
研究的目的:
- 开发一种有效的方法来制备球形多孔碳 (SPC).
- 为了利用基于煤炭的湿酸作为先进阴极材料的前体.
- 为了提高离子混合电容器的性能.
主要方法:
- 喷雾干燥以煤为基础的湿酸.
- 化学激活过程以创建多孔的碳结构.
- 使用 SPC 阴极制造和测试 SIC 设备.
主要成果:
- SPC表现出高特异性表面积和狭窄的孔径分布.
- 该SPC阴极在0.05Ag-1时实现了223Fg-1的容量.
- SIC 显示出高能量密度 (179.8 Wh kg-1) 和出色的循环稳定性 (89.4% 10,000 次循环后的保留).
结论:
- 开发的SPC是SIC有效的高容量阴极材料.
- 这种方法为高性能混合电容提供了可行的途径.
- 该研究推进了使用可持续前体的储能解决方案.
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