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Updated: Jun 13, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

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铜伊米达佐林-伊米因协调化合物作为Cu/Al复合物的前体

Ivan Antsiburov1,2, Johannes Stephan1,2, Richard J J Weininger1,2

  • 1Technical University of Munich, School of Natural Sciences, Department of Chemistry, Chair of Inorganic and Metal-Organic Chemistry Lichtenbergstrasse 4, 85748 Garching, Germany.

Inorganic chemistry
|September 11, 2024
PubMed
概括

合成了新的铜 (I) 复合物与固体阻碍的伊米达佐林-2-胺配体. 这些复合体,包括线性和四面体结构,使用各种光谱和晶体学方法进行了表征.

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In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For instance, the four valence electrons of carbon overlap with electrons from four hydrogen atoms to form CH4. The one valence electron leaves sodium and adds to the seven valence electrons of chlorine to form the ionic formula unit NaCl (Figure 1a). Transition metals do not normally bond in this fashion. They primarily form coordinate covalent bonds, a...
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