硫修饰对/离子电池基碳材料结构和电化学性能的影响
Zihui Ma1, Zhe Wen1,2, Yan Song1,3
1CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China.
Nanomaterials (Basel, Switzerland)
|September 13, 2024
概括
硫化基碳 (SPC-800) 提高了离子电池 (LIB) 和离子电池 (SIB) 的阳极性能. 这种无序的碳材料提供了优越的特定容量,指导了先进电池阳极的发展.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 煤焦油 (CTP) 由于其特性,是电池阳极的成本效益高的碳前体.
- 开发用于离子电池 (LIB) 和离子电池 (SIB) 的高性能阳极对于储能进步至关重要.
研究的目的:
- 来自CTP的硫化基碳 (SPC-800) 的合成和特征.
- 评估SPC-800作为LIB和SIB的阳极材料的电化学性能.
主要方法:
- 煤焦油在350°C时与硫反应,然后在800°C时碳化,产生SPC-800.
- 结构分析比较SPC-800与碳化的CTP (PC-800).
- 在LIB和SIB中作为阳极的SPC-800的电化学测试.
主要成果:
- 与PC-800相比,SPC-800具有更混乱的结构和更大的层间距.
- 作为一个LIB阳极,SPC-800在0.1 A g-1.1时实现了478.1 mAh g-1的可逆特异容量.
- 作为SIB阳极,SPC-800在20 mA g-1.1下提供220.9 mAh g-1的容量.
结论:
- 硫化和碳化CTP为下一代电池创造了有效的阳极材料.
- SPC-800显示出作为LIB和SIB的高性能阳极的潜力.
- 这项研究为设计使用修改CTP的先进电池阳极提供了途径.
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