增强的稀土元素回收与交叉链接的甲基-兰坦化结合在基于泡的分离
Luis E Ortuno Macias1, Honghu Zhang2, Benjamin M Ocko2
1Department of Chemical Engineering, The City College of New York, New York, NY, 10031, USA; The Benjamin Levich Institute for PhysicoChemical Hydrodynamics, The City College of New York, New York, NY, 10031, USA.
Journal of colloid and interface science
|September 13, 2024
概括
甲增强了与化物结合的膜,以改善稀土元素 (REE) 的回收. 这种交叉连接方法稳定了接口层,优化了基于泡的分离过程.
科学领域:
- 生物分子工程是生物分子工程.
- 材料科学是一种材料科学.
- 化学工程是化学工程的组成部分.
背景情况:
- 兰化物结合标签 (LBT) 可以选择性地结合兰化物离子,为能源密集的稀土元素 (REE) 分离工艺提供可持续的替代方案.
- 这些可以吸附到空气/水界面,从而使基于泡的REE回收成为可能.
- 甲是一种交叉结合剂,可能会在接口处稳定这些膜.
研究的目的:
- 调查谷氨基用于增强与胺结合的LBT的吸附和界面稳定.
- 评估甲基交联对REE回收界面膜稳定性和性能的影响.
主要方法:
- 用吊滴压力计测量了表面活动.
- 界面膜的稳定性通过扩张和剪切表面风学进行评估.
- 使用X射线反射率和近完全反射的X射线光度来确定表面密度和分子排列.
主要成果:
- 甲基交叉链接显著增强了甲酸对空气-水接口的吸附,形成更厚的接口结构.
- 交叉连接的薄膜表现出改善的扩张和剪切界面的质性质.
- 甲有效地稳定了接口膜,促进了REE提取.
结论:
- 甲基作为一个有效的交叉链接器,以提高 LBT 的性能在基于泡的 REE 恢复.
- 这种方法为传统泡稳定剂提供了可行的替代方案,优化了基于生物分子的REE提取.
- 这项研究展示了一种新的方法,用于整合甲以改善界面膜的特性,以有效地分离REE.
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