关于环氧/氨基/甲混合物的固化和热性能的研究
Cong Peng1, Tao Luo1,2, Zhanjun Wu1,3
1College of Fiber Engineering and Equipment Technology, Jiangnan University, Wuxi 214401, China.
Materials (Basel, Switzerland)
|September 14, 2024
概括
在环氧系统中添加双A型甲 (BAPH) 增强了交联和热稳定性. 这种新型的环氧/乙烯热固体表现出改善的玻璃过渡温度和显著增加的碳产量,用于先进的材料应用.
科学领域:
- 聚合物科学 聚合物科学
- 材料化学 材料化学
背景情况:
- 环氧树脂是广泛使用的热.
- 提高它们的热稳定性和燃烧率对于高性能应用至关重要.
研究的目的:
- 为了研究双A型甲 (BAPH) 对环氧/胺热的固化动力学和热特性的影响.
- 探索BAPH作为环氧树脂修饰剂的潜力.
主要方法:
- 不同扫描热量计 (DSC) 用于固化动力学.
- 福里埃变换红外光谱 (FTIR) 用于反应特征.
- 动态机械分析 (DMA) 和热重力测量分析 (TGA) 用于测量热性能.
- 原子力显微镜 (AFM) 用于形态学.
- 实时热重力测量分析-质谱测量 (TG-MS) 用于热解分析.
主要成果:
- 添加BAPH降低了固化的平均激活能量.
- FTIR证实了BAPH和DDS之间的反应.
- 玻璃过渡温度从181°C增加到195°C.
- 在800°C下,炭水化物产量显著增加,从16%增加到59.6%.
- 没有观察到相位分离,这表明共聚合物形成.
结论:
- 甲促进了环氧/氨基系统的交叉连接.
- 修改后的热固体表现出增强的热稳定性和燃烧效率.
- 硬化后的混合物很可能形成具有改进材料特性的共聚物.
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