评估在海水中作为二碳酸丰富溶液储存的二氧化碳2的限制
Selene Varliero1, Samira Jamali Alamooti1, Francesco Pietro Campo2,3
1Department of Chemistry, Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano, Via Luigi Mancinelli 7, 20131 Milano, Italy.
Molecules (Basel, Switzerland)
|September 14, 2024
概括
如果二氧化碳度保持在1500μmol/L以下,将二氧化碳 (CO2) 储存在海水中的二氧化碳酸盐中是长期稳定的,为地质储存提供了一个海洋友好的替代方案.
科学领域:
- 海洋化学 海洋化学
- 环境科学环境科学
- 碳捕获和储存是碳捕获和储存的一种方式.
背景情况:
- 二氧化碳 (CO2) 的地质储存面临着关于长期稳定性和环境影响的挑战.
- 在海水中将二氧化碳溶解为二碳酸盐离子是一种潜在的替代储存方法.
- 评估富含二氧化碳碳酸盐溶液的化学稳定性和环境安全性至关重要.
研究的目的:
- 为了评估二氧化碳作为二碳酸盐在海水中被吸收的长期化学稳定性.
- 随着时间的推移,监测这些溶液的关键物理化学性质.
- 确定二氧化碳二氧化碳溶液在海洋环境中保持稳定的条件.
主要方法:
- 实验对自然和人造海水进行了长达三个月的试验.
- 监测pH值,溶解的无机碳和性.
- 利用试点工厂进行大规模的二碳酸盐处理和实验室实验,添加二碳酸.
主要成果:
- 富含二碳酸盐的海水溶液表现出超过三个月的稳定性.
- 只要总碳度的增加不超过大约1000-1500μmol/L的临界值,就保持稳定.
- 在这种度范围内,物理化学特性保持一致.
结论:
- 海水可以作为碳酸作为长期储存二氧化碳的稳定介质.
- 关键碳度值是确保储存稳定的关键.
- 这种方法为地质二氧化碳储存提供了一个有希望的,环保的替代方案.
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