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相关概念视频

Ionic Bonding and Electron Transfer02:48

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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In some cases, there are seemingly more than one valid Lewis structures for molecules and polyatomic ions. The concept of formal charges can be used to help predict the most appropriate Lewis structure when more than one reasonable structure exists.
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In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
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Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
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SF6负离子形成在电荷转移实验中的负离子形成

Sarvesh Kumar1,2, Masamitsu Hoshino3, Boutheïna Kerkeni4,5

  • 1Atomic and Molecular Collisions Laboratory, CEFITEC-Centre of Physics and Technological Research, Department of Physics, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal.

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概括

与六化硫 (SF6) 的碰撞产生碎片离子,主要是SF5-. 这项研究更新了以前的发现,提供了关于离子形成和电子状态的新数据.

关键词:
阳离子的形成.转移费用 转移费用 转移费用 转移费用能量损失,能量损失.质谱测量质谱测量质谱测量质谱测量质量测量质谱测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量质量测量硫六化物硫六化物

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科学领域:

  • 物理化学 物理化学
  • 化学物理 化学物理
  • 原子和分子碰撞 原子和分子碰撞

背景情况:

  • 扩展了之前关于K + SF6碰撞的离子对形成研究.
  • 解决了在临时负离子中复杂的分子内能量再分配问题.

研究的目的:

  • 更新和扩展之前对K + SF6碰撞的离子对形成研究.
  • 为了研究碎片离子形成和能量损失光谱.
  • 用量子化学计算来支持实验发现.

主要方法:

  • 飞行时间质谱测量检测碎片离子.
  • 碰撞在广泛的能量范围内进行 (10.7213.1 eV).
  • 对未被占用的分子轨道进行量子化学计算.

主要成果:

  • SF5-是主要的离子 (>70%的产量),其次是SF6-和F-.
  • 小离子包括SF3-和F2-,有微量S-.
  • 离子的能量损失光谱为碰撞动态提供了洞察力.

结论:

  • 实验和理论结果阐明了K + SF6碰撞中离子形成的机制.
  • 突出了共振和赖德伯格状态在离子形成中的作用.
  • 提供了对碰撞动态和碎片化路径的全面了解.