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SF6负离子形成在电荷转移实验中的负离子形成
Sarvesh Kumar1,2, Masamitsu Hoshino3, Boutheïna Kerkeni4,5
1Atomic and Molecular Collisions Laboratory, CEFITEC-Centre of Physics and Technological Research, Department of Physics, Universidade NOVA de Lisboa, 2829-516 Caparica, Portugal.
Molecules (Basel, Switzerland)
|September 14, 2024
概括
与六化硫 (SF6) 的碰撞产生碎片离子,主要是SF5-. 这项研究更新了以前的发现,提供了关于离子形成和电子状态的新数据.
科学领域:
- 物理化学 物理化学
- 化学物理 化学物理
- 原子和分子碰撞 原子和分子碰撞
背景情况:
- 扩展了之前关于K + SF6碰撞的离子对形成研究.
- 解决了在临时负离子中复杂的分子内能量再分配问题.
研究的目的:
- 更新和扩展之前对K + SF6碰撞的离子对形成研究.
- 为了研究碎片离子形成和能量损失光谱.
- 用量子化学计算来支持实验发现.
主要方法:
- 飞行时间质谱测量检测碎片离子.
- 碰撞在广泛的能量范围内进行 (10.7213.1 eV).
- 对未被占用的分子轨道进行量子化学计算.
主要成果:
- SF5-是主要的离子 (>70%的产量),其次是SF6-和F-.
- 小离子包括SF3-和F2-,有微量S-.
- 离子的能量损失光谱为碰撞动态提供了洞察力.
结论:
- 实验和理论结果阐明了K + SF6碰撞中离子形成的机制.
- 突出了共振和赖德伯格状态在离子形成中的作用.
- 提供了对碰撞动态和碎片化路径的全面了解.
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