评估一个体积平均物种运输模型与微宏合用于突破曲线预测的评估
Parham Mobadersani1, Naine Tarun Bharat1, Krishna M Pillai1
1Laboratory for Flow and Transport Studies in Porous Media, University of Wisconsin-Milwaukee, Milwaukee, WI 53211, USA.
Molecules (Basel, Switzerland)
|September 14, 2024
概括
用于模拟水过器中的污染物运输的体积平均化方法 (VAM) 与模拟和实验存在差异. 时间限制的违反被确定为使用量平均方法的主要原因.
科学领域:
- 环境工程 环境工程
- 化学工程是化学工程的重要组成部分.
- 流体动力学 流体动力学
背景情况:
- 在多孔水过器中的污染物运输是使用对流-分散方程建模的.
- 体积平均方法 (VAM) 为污染物度预测提供了宏观方程.
- 存在两个VAM方程:一个是总分散张量,另一个是吸附诱导向量.
研究的目的:
- 用直接数值模拟 (DNS) 和实验数据来解决和比较VAM衍生的宏观方程.
- 为了验证基于微宏合的VAM模型用于多孔水过器.
- 确定污染物运输建模的VAM中的局限性和潜在改进.
主要方法:
- 使用3D单元单元的列测试,在1D中解决VAM衍生的方程.
- 将模拟的突破曲线 (BTC) 与来自BCC型单元格的DNS结果进行比较.
- 根据实验数据进行验证,使用热和零价值铁去除和.
主要成果:
- 从VAM模型中模拟的BTC显示与DNS和实验结果不一致.
- 差异表明需要在VAM中使用替代的闭包配方.
- 在所有比较中都始终观察到时间限制的违规行为.
结论:
- 目前的VAM配方,特别是关于时间限制,不足以准确预测水过器中的污染物运输.
- 需要进一步的研究来开发VAM的改进的闭包配方.
- 解决时间限制违规问题对于提高VAM在环境应用中的预测能力至关重要.
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