了解基于Fe-V-W-Al的薄膜的异常热电行为
Kavita Yadav1, Yuya Tanaka1, Artoni Kevin R Ang1,2
1Toyota Technological Institute, Hisakata 2-12-1, Tempaku, Nagoya 468-8511, Japan.
ACS applied materials & interfaces
|September 14, 2024
概括
Fe-V-W-Al薄膜具有增强的热电特性. 在n-Si基板上的无形薄膜显示出高的Seebeck系数和功率因子,这导致了能源采集应用的优越功率.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 纳米技术纳米技术
背景情况:
- 热电材料对于废热回收至关重要.
- 基于Fe-V-W-Al的薄膜为热电应用提供了潜力.
- 优化薄膜结构和特性是提高热电性能的关键.
研究的目的:
- 为了研究Fe-V-W-Al薄膜的热电和热行为.
- 探索氧气压力和基板类型对薄膜性能的影响.
- 在薄膜设备中实现高热电性能.
主要方法:
- 用于薄膜沉积的射频磁铁喷射技术.
- 不同的氧气压力 (0.1-1.0 × 10−2 Pa) 和基板 (n-Si,p-Si,未化Si).
- 结构,热电和热性能的表征.
主要成果:
- 在较高的氧气压力下形成的无形结构,在较低的氧气压力下形成的bcc-Heusler.
- 在n-Si上的无形Fe-V-W-Al膜显示Seebeck系数为~-1098μV K-1 .
- 实现了高功率系数~33.9 mW m-1 K-2 和功率的数字~3.9 在320K.
- 观察到2.75 Wm-1 K-1 的低导热率.
结论:
- 在n-Si上的中度氧化无形Fe-V-W-Al薄膜具有特殊的热电特性.
- 金属无形氧化物和绝缘基板的复合效应有助于高性能.
- 这些发现为高效的热电能转换提供了一个有希望的途径.
相关概念视频
Theory of Metallic Conduction
1.3K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.3K
Biasing of Metal-Semiconductor Junctions
222
Biasing metal-semiconductor junctions involves applying a voltage across the junction. Specifically, the metal is connected to a voltage source, while the semiconductor is grounded. This technique is essential for controlling the direction and magnitude of current flow in electronic devices, including diodes, transistors, and photovoltaic cells.
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
222
Joule-Thomson Effect
3.3K
The Joule-Thomson effect, also known as the Joule-Kelvin effect, describes the temperature change of a fluid when it is forced through a valve or porous plug while keeping it in a thermally insulated environment. This experiment is called a throttling process. This is an important effect widely used in refrigeration and the liquefaction of gases.
This experiment forces high-pressure gas through a throttle valve or a porous plug to a lower-pressure region. The gas expands as it passes through to...
This experiment forces high-pressure gas through a throttle valve or a porous plug to a lower-pressure region. The gas expands as it passes through to...
3.3K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K


