相关实验视频
Updated: Jun 13, 2025

06:58
Zinc-Sponge Battery Electrodes that Suppress Dendrites
Published on: September 29, 2020
4.3K
水性离子电池的基阴极:机制,挑战和策略
Kaiyue Zhu1,2, Weishen Yang1,2
1State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Accounts of chemical research
|September 16, 2024
概括
本研究为离子电池 (ZIB) 中的基于的阴极提供了路线图,重点关注稳定的结构和了解溶解机制,以提高性能和寿命.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 离子电池 (ZIB) 由于安全性,成本和环保性,对大规模储能充满希望.
- 基于的化合物具有高容量,但在ZIB中面临溶解和相变的挑战.
- 关于基阴极中的活性相,储存机制和溶解途径的不确定性仍然存在.
研究的目的:
- 为ZIB中基于的正极提供全面的路线图.
- 为了将内在的晶体结构与设计高容量和稳定的材料的性能相关联.
- 阐明能量储存和不稳定机制,以便有效优化.
主要方法:
- 分析内在的晶体结构及其与电化学性能的相关性.
- 研究能量储存和不稳定机制.
- 对增强循环稳定性的策略进行审查,包括电解质调制,涂层,现场转换,离子预间接和离子交换.
主要成果:
- 稳定的[VO6]八面体对于ZIB中的高性能基氧化物至关重要,避免不活性[VO4]四面体和不稳定的[VO5]方形金字塔.
- 能量储存涉及H2O/H+/Zn2+的共同插入,间层水增强速率和循环性能.
- 副产品的形成 (例如,基本盐,Zn3(OH) 2V2O7·2H2O) 对长期稳定性产生影响,需要采取减轻V溶解的策略.
结论:
- 设计基于的阴极需要保持稳定的[VO6]八面体,并了解入物种和副产品的作用.
- 电解质调制和接口工程等策略是提高循环稳定性和减少V溶解的关键.
- 未来的研究应该集中在原子尺度机制阐明,速率-性能提升和实际ZIB应用扩展上.
相关概念视频
Batteries and Fuel Cells
27.1K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.1K
Voltaic/Galvanic Cells
56.9K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.9K
Voltammetry: Stripping Methods
192
Anodic Stripping Voltammetry (ASV), Cathodic Stripping Voltammetry (CSV), and Adsorptive Stripping Voltammetry (AdSV) are electrochemical techniques used to determine trace amounts of analytes in solution. These methods involve applying a potential to an electrode and measuring the resulting current.
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
Anodic Stripping Voltammetry (ASV)
ASV is used to determine metals and metalloids at trace levels. It involves two steps: deposition and stripping. First, a negative potential is applied to the...
192
Standard Electrode Potentials
43.5K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
43.5K
Electrodeposition
612
Electrodeposition is a technique used to separate an analyte from interferents by electrochemical processes. Here, the analyte is a metal ion that can be deposited on an electrode immersed in the sample solution. The electrochemical setup consists of an anode and a cathode. When an electric current is applied to the setup, oxidation occurs at the anode. At the cathode, which consists of a large metal surface, metal ions undergo reduction and deposit onto the surface.
Electrodeposition can...
Electrodeposition can...
612
Voltammetry: Factors Affecting Measurements
137
A current produced due to the redox reactions of the analyte at the working and auxiliary electrodes is called a faradaic current. The reaction can be divided into two types. The current generated due to the reduction of the analyte is called cathodic current, and it carries a positive charge. In contrast, the current produced by analyte oxidation is known as an anodic current, and it has a negative charge. The applied potential at the working electrode determines the faradaic current flow, and...
137

