来自氨基酸和油酸的铁电水凝
Erica Pensini1,2, Peter Meszaros1, Nour Kashlan1
1School of Engineering, University of Guelph, 50 Stone Road East, Guelph, ON N1G 2W1, Canada.
iScience
|September 16, 2024
概括
研究人员使用氨基酸和油酸开发了新的铁电生物基材料. 这些高度水合的凝具有压电性,可用于医学和清洁能源采集.
科学领域:
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
- 物理化学 物理化学
背景情况:
- 开发具有高含水量 (≈90 wt%) 的铁电生物基材料是一个重大挑战.
- 现有的材料往往缺乏必要的水分或特定的功能组,以达到所需的性能.
研究的目的:
- 开发具有高含水量的新型铁电生物基材料.
- 研究这些水凝的结构和电气特性.
- 探索它们在医学和能源采集方面的潜在应用.
主要方法:
- 使用氨基酸 (lysine, arginine) 和油酸合成水凝.
- 减弱总反射率 - 里叶变换红外光谱学 (ATR-FTIR) 来分析键.
- 同步射线小角度X射线散射 (SAXS) 用于确定晶体结构.
- 极化光显微镜和剪切神经学来描述凝的特性.
- 循环电压测量来证明压电.
主要成果:
- 成功合成了含有约90%重量%水分的水凝.
- ATR-FTIR证实了 lysine 的 NH/CH 组与水之间的键,从而产生导电溶液.
- 萨克斯发现了由素-油酸相互作用形成的状晶体结构.
- 极化光显微镜和神经病理学确定了具有柱状六角和双连续海绵晶体结构的双折射凝.
- 循环电压测量证明了压电行为,材料在电场下变形和经历相变.
结论:
- 开发了具有高含水量 (高达90%重量%) 的新型铁电生物基水凝.
- 这些材料由于其独特的结构和组成,具有压电特性.
- 开发的压电材料有望用于医疗设备和清洁能源采集技术的应用.
相关概念视频
Water: A Bronsted-Lowry Acid and Base
The reaction between a Brønsted-Lowry acid and water is called acid ionization. For example, when hydrogen fluoride dissolves in water and ionizes, protons are transferred from hydrogen fluoride molecules to water molecules, yielding hydronium ions and fluoride ions:
Ions as Acids and Bases
Salts with Acidic Ions
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Salts are ionic compounds composed of cations and anions, either of which may be capable of undergoing an acid or base ionization reaction with water. Aqueous salt solutions, therefore, may be acidic, basic, or neutral, depending on the relative acid-base strengths of the salt’s constituent ions. For example, dissolving the ammonium chloride in water results in its dissociation, as described by the equation:
Precipitation and Co-precipitation
Precipitation and coprecipitation methods can be used to separate a mixture of ions in a solution. In qualitative inorganic analysis, ions that form sparingly soluble precipitates with the same reagent are separated based on the differences in solubility products. For example, consider the separation of Cu(II) and Fe(II) ions by precipitation as insoluble sulfides. First, copper(II) sulfide is precipitated by the addition of acidic H2S, where the dissociation of H2S is suppressed. Adding H2S...
Coagulation
Colloidal solids are solid particles suspended in solution. They are usually negatively charged, attracting a compact primary layer of positively charged ions, which attract more counterions to form an electrical double layer. Electrostatic repulsion between the charged double layers prevents the particles from colliding, stabilizing the colloids. These solids are often undesirable because they can contain toxins that are difficult to remove. Coagulation is a technique that helps aggregate and...
Microbes and Other Elemental Cycles
Microbial activity plays a pivotal role in the biogeochemical cycling of iron and manganese, especially at the redox gradients characteristic of stratified aquatic environments. These cycles are driven by microbial transformations between oxidized and reduced forms of the metals, allowing organisms to exploit them for metabolic energy and structural purposes.Iron Cycling Across Redox GradientsIn neutral, oxygen-rich surface waters, iron is predominantly found in its oxidized, insoluble ferric...
Acid Mine Drainage
Mining activities that disturb sulfide-rich rocks, particularly those containing pyrite (FeS₂), initiate a cascade of geochemical and microbiological processes with serious environmental implications. When exposed to air and water, pyrite undergoes oxidation, releasing sulfate, ultimately forming sulfuric acid and mobilizing heavy metals into surrounding water systems. This phenomenon, known as acid mine drainage (AMD), results in low pH waters laden with toxic elements that threaten aquatic...


