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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Charge on a Conductor01:26

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An interesting property of a conductor in static equilibrium is that extra charges on the conductor end up on its outer surface, regardless of where they originate. Consider a hollow metallic conductor with a uniform surface charge density. Since the conductor itself is in electrostatic equilibrium, there should not be any electric field inside the conductor. Now, assume a Gaussian surface enclosing the hollow portion. Applying Gauss's law, the inner surface of the hollow conductor will not...
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Ionic Strength: Effects on Chemical Equilibria01:19

Ionic Strength: Effects on Chemical Equilibria

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The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
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Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

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Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
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Charging Conductors By Induction01:15

Charging Conductors By Induction

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The Earth is a good conductor of electricity, and it is so big that it can be considered an infinite source or sink of charges. It can easily exchange charges with any matter.
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
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Band Theory02:35

Band Theory

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When two or more atoms come together to form a molecule, their atomic orbitals combine and molecular orbitals of distinct energies result. In a solid, there are a large number of atoms, and therefore a large number of atomic orbitals that may be combined into molecular orbitals. These groups of molecular orbitals are so closely placed together to form continuous regions of energies, known as the bands.
The energy difference between these bands is known as the band gap.
Conductor, Semiconductor,...
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固态电池混合离子电子导电极中的空间电荷效应.

Shu-Han Chen1, Chia-Chin Chen1

  • 1Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan. chiachin@ntu.edu.tw.

Physical chemistry chemical physics : PCCP
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概括
此摘要是机器生成的。

了解混合离子电子导体的理解

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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 固态化学 固态化学

背景情况:

  • 混合离子电子导体对于能源设备至关重要.
  • 这些材料的界面化学是不太了解的.
  • 这影响了充电储存和运输.

研究的目的:

  • 为了研究混合导体异质连接处的空间电荷效应.
  • 为了统一批量和界面缺陷化学与电化学潜力.
  • 开发一个界面现象的预测框架.

主要方法:

  • 缺陷的化学原理. 缺陷的化学原理.
  • 统一处理散装和界面条件.
  • 电化学潜力的整合.电化学潜力的整合.

主要成果:

  • 预测异质连接处的内置潜力.
  • 配置文件空间电荷分布.
  • 评估接口电荷存储和运输.
  • 在纳米晶体电极中突出显示尺寸和兴奋剂效应.

结论:

  • 为理解混合导体异质连接提供了一个全面的框架.
  • 允许在电化学设备中设计接口.
  • 将理论处理与实验表征联系起来 (例如,库洛米度定位,导电率,电容).