先进的核心外空心碳纳米纤维用于离子电池中的离子和电子可访问性
Zhisong He1, Yu Liu1, Xiaozhi Yuan1
1State Key Laboratory of Environment-Friendly Energy Materials, Engineering Research Center of Biomass Materials, Ministry of Education, School of Materials and Chemistry, Southwest University of Science and Technology, Mianyang, Sichuan 621010, China. xijunwei1992@swust.edu.cn.
概括
新型核心外空心碳纳米纤维 (HCNFs) 提高离子电池的性能. 它们独特的结构改善了电解质透和离子运输,从而提高了速度能力和容量保留.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- 开发先进的电极材料对于高性能储能设备至关重要.
- 碳基纳米材料为电池应用提供了有前途的特性.
- 空洞纳米结构可以改善离子扩散和电解质可访问性.
研究的目的:
- 合成和表征一个维的核心外空心碳纳米纤维 (HCNFs).
- 为了研究离子电池中HCNFs的电化学性能.
- 阐明控制离子运输动态的结构属性关系.
主要方法:
- 用于HCNF制造的同轴电.
- 脱乙和碳化用于材料加工.
- 电化学测试用于评估电池性能.
主要成果:
- 合成的HCNF具有化硬碳外和内部碳核.
- 核心外空洞结构有利于电解质透和离子/电子运输.
- 在2Ag-1时实现了77%的高保留率,证明了卓越的速度性能.
- 由于独特的HCNF架构,优化了运输动态.
结论:
- 设计的核心外空洞结构显著提高了的运输.
- 高CNF显示出作为高性能离子电池的先进电极材料的巨大潜力.
相关概念视频
Ionic Bonds
118.1K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.1K
Batteries and Fuel Cells
27.1K
A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
27.1K
Ions and Ionic Charges
66.4K
In ordinary chemical reactions, the nucleus — which contains the protons and neutrons of each atom and thus identifies the element — remains unchanged. Electrons, however, can be added to atoms by transfer from other atoms, lost by transfer to other atoms, or shared with other atoms. The transfer and sharing of electrons among atoms govern the chemistry of the elements. During the formation of some compounds, atoms gain or lose electrons to form electrically charged particles called...
66.4K
Voltaic/Galvanic Cells
56.9K
Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
56.9K
Formation of Complex Ions
23.5K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.5K
Facilitated Transport
11.3K
The chemical and physical properties of plasma membranes cause them to be selectively permeable. Since plasma membranes have both hydrophobic and hydrophilic regions, substances need to be able to transverse both regions. The hydrophobic area of membranes repels substances such as charged ions. Therefore, such substances need special membrane proteins to cross a membrane successfully. In facilitated transport, also known as facilitated diffusion, molecules and ions travel across a...
11.3K


