使用生物聚合物生产的响应表面方法和生物基聚氨泡合成的响应表面方法,优化葡萄的液化
Furkan Çolakoğlu1, Emre Akdoğan1, Murat Erdem1
1Department of Chemistry, Faculty of Science, Eskişehir Technical University, Eskişehir, Turkiye.
Turkish journal of chemistry
|September 19, 2024
概括
研究人员优化了葡萄末液化,以获得可持续的生物聚合物. 由此产生的生物基刚性聚氨泡 (RPUF) 对环保应用具有有前途的性能.
科学领域:
- 可持续化学 可持续化学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 基于石油的产品带来了环境和经济挑战.
- 越来越需要可持续和经济的替代品.
- 葡萄末是一种丰富的农业废物,具有价值化潜力.
研究的目的:
- 为了优化葡萄末的溶热液化.
- 从衍生生物聚合物中合成和表征生物基刚性聚氨泡 (RPUF).
- 评估使用葡萄末作为RPUF生产的原料的可行性.
主要方法:
- 使用响应表面方法 (RSM) 与中央复合设计 (CCD) 的溶热液化过程优化.
- 生物聚合物的物理化学特征 (基数,酸数,粘度).
- 生物基RPUF的合成和表征 (导热性,闭细胞含量,表面密度,压力强度).
主要成果:
- 优化反应条件 (165°C,4.25%的催化剂负载,50分钟) 产生了81.3%的液化.
- 生物聚合物具有与商业聚合物相似的特性.
- 生物基RPUF表现出有利的特性:导热率 (31.3mW/m·K),闭细胞含量 (71.1%),表面密度 (33.4kg/m3) 和压力强度 (105.3kPa).
结论:
- 葡萄末的溶热液化是生产生物聚合物的有效方法.
- 优化的生物聚合物可用于合成高性能生物基RPUF.
- 这项研究提出了将农业废物转化为有价值材料的可持续途径,减少对石油制品的依赖.
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