在水性分散中使用硫酸盐功能化单体的结合聚合物纳米颗粒的无表面活性剂制备
Marcin Gwiazda1, Benjamin J Lidster1, Charlotte Waters1
1Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Journal of the American Chemical Society
|September 19, 2024
概括
研究人员开发了一种新的方法,可以在没有表面活性剂的情况下制造稳定的聚合物纳米粒子. 这种方法使用带电单体,简化了光电子设备的生产.
科学领域:
- 聚合物化学
- 材料科学
- 纳米技术
背景情况:
- 结合的聚合物纳米颗粒 (CPN) 是通过苏子-米亚拉交叉合微乳液聚合合成的.
- 需要高度的表面活性剂来稳定,但很难去除并影响设备的性能.
研究的目的:
- 开发一种无表面活性剂的方法来制备稳定的CPN分散物.
- 允许在光电子设备中使用CPN,而不会造成残留表面活性物质的污染.
主要方法:
- 使用一种具有充电硫酸盐组的新型单体 (2,7-二-9,9-二) -9H-.
- 采用微乳液聚合法,使用充电单体的不同摩尔比率 (2.0-20.0mol%).
- 合成的多甲 (PFO) 和多甲 (PF8T2).
主要成果:
- 在没有添加表面活性剂的情况下实现稳定的微乳液分散.
- 纳入5.0mol%的充电单体导致表面电位低于-40mV的分散.
- 合成的聚合物表现出超过10千克的摩尔质量 (M).
结论:
- 这种新型充电单体通过静电排斥有效地稳定了微乳液.
- 这种无表面活性剂的方法简化了光电子产品的CPN分散制剂.
- 该方法广泛适用于多分散,消除了合成后的净化步骤.
更多相关视频
10:16Electroactive Polymer Nanoparticles Exhibiting Photothermal Properties
Published on: January 8, 2016
13.9K
07:01Preparation of Hollow Polystyrene Particles and Microcapsules by Radical Polymerization of Janus Droplets Consisting of Hydrocarbon and Fluorocarbon Oils
Published on: January 25, 2018
9.9K
相关概念视频
Colloidal precipitates
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
Factors Affecting Dissolution: Particle Size and Effective Surface Area
Dissolution kinetics, an essential aspect of oral drug delivery, is significantly influenced by the drug's particle size. According to the Noyes-Whitney dissolution model, the dissolution rate correlates directly with the drug's surface area. The larger the surface area, the higher the drug's solubility in water, leading to a faster drug dissolution rate. Reducing particle size increases the effective surface area, enhancing the dissolution process. Micronization and nanosizing are employed to...
Superplasticizers
Superplasticizers are advanced admixtures that enhance the workability of concrete by lowering the water content without compromising the strength of the material. These substances are highly effective water reducers, improving concrete flow, making it easier to work with, and enabling concrete to reach inaccessible areas or densely reinforced sections without mechanical vibration. The key components in superplasticizers are either sulfonated melamine or naphthalene formaldehyde condensates,...
