适当的火焰喷雾处理加剧了残留聚乙烯薄膜的热氧化降解
Weiqi Chen1, Dong Wang2, Chaoli Guo3
1State Key Laboratory of Herbage Improvement and Grassland Agro-ecosystems, College of Ecology, Lanzhou University, Lanzhou 730000, Gansu Province, China; Gansu Institute of Metrology, Lanzhou 730000, Gansu Province, China.
The Science of the total environment
|September 19, 2024
概括
热处理迅速降解聚乙烯 (PE) 农业薄膜,减少土壤污染. 适度的火焰喷雾 (220340°C) 为干旱土地农业中的PE薄膜废物管理提供了有效的解决方案.
科学领域:
- 农业科学 农业科学
- 聚合物科学 聚合物科学
- 环境科学 环境科学
背景情况:
- 塑料薄膜覆盖增加了干地农业的作物产量,但留下了有害的聚乙烯 (PE) 残留物.
- 持续的PE薄膜废物损害了土壤的健康,需要有效的降解方法.
研究的目的:
- 通过火焰喷雾来研究中度热处理对聚乙烯 (PE) 残膜快速降解的有效性.
- 描述PE薄膜在火焰喷后的物理和化学变化.
主要方法:
- 使用自制的火焰喷雾设备来控制PE残渣薄膜的热暴露.
- 分析了微形态 (SEM-EDX),功能组 (FTIR),结晶性 (XRD) 和热降解 (TGA-FTIR).
主要成果:
- 火焰喷导致PE薄膜的重量减轻 (9.3915.35%) 和表面变化 (坑,裂).
- 观察到氧含量增加 (O/C比) 和含氧功能组和双键的形成.
- 降解在220°C开始,主要的挥发性产品在340°C~440°C之间释放;最佳分解发生在220°C~340°C.
结论:
- 适度的火焰喷有效地加速了PE残留膜的分解.
- 建议控制温度范围 (220°C340°C),以减轻由降解副产品带来的环境风险.
- 这些发现为农业领域的PE薄膜废弃物管理提供了科学基础.
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