用于光学数据存储应用的诱导可调节带隙.
Surbhi Agarwal1, D K Dwivedi1, Pooja Lohia2
1Photonics and Photovoltaic Research Lab, Department of Physics and Material Science, Madan Mohan Malviya University of Technology Gorakhpur 273010 India todkdwivedi@gmail.com.
RSC advances
|September 20, 2024
概括
本研究探讨了用于相变存储器 (PCM) 应用的基于Te的薄膜. 研究的材料显示了对光子设备有前途的光学和电子性能.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 光电学是指光电子产品.
背景情况:
- 阶段变换内存 (PCM) 对人工智能应用至关重要,因为它需要具有高热稳定性和快速运行的材料.
- 当前的PCM材料在同时实现这些关键性能特征时面临着挑战.
- 基于Te的石灰化物材料正在研究先进的记忆技术.
研究的目的:
- 为了研究Te1-GeSe0.5) Y (x = 0.05,0.1,0.15) 薄膜的光学和电子特性.
- 评估它们在光子应用和人工智能启发的计算方面的潜力.
- 了解材料组成和性能之间的关系.
主要方法:
- 使用热蒸发进行薄膜沉积.
- 通过X射线衍射 (XRD) 进行结构性表征.
- 使用扫描电子显微镜 (SEM) 进行表面形态分析.
- 使用能量分散式X射线光谱 (EDX) 进行元素组成分析.
- 使用紫外线可见光谱光度计 (5002500 nm) 确定光学属性.
- 分析光学参数,包括折射率 (n),灭绝系数 (k),吸收系数 (α) 和光学带隙.
- 应用陶克关系和乌尔巴赫关系.
- 使用Wemple-DiDomenico模型计算非线性折射率.
- 介电性质和能量损失函数的确定.
主要成果:
- 指示的光能带隙允许间接过渡.
- 随着Y含量增加,观察到增强的光学参数.
- 折射率,灭绝系数和吸收系数被系统地确定.
- 计算了非线性光学性质,介电性质和能量损失函数.
- 结构,形态和组成分析证实了薄膜的完整性.
结论:
- 研究的基于Te的薄膜表现出有利的光学和电子性能.
- 增强的光学参数表明它适用于各种光子应用.
- 这些材料显示出在先进的人工智能硬件中使用的潜力.
相关概念视频
UV–Vis Spectroscopy: Molecular Electronic Transitions
3.0K
In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this...
3.0K
IR Absorption Frequency: Hybridization
1.5K
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that...
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that...
1.5K
IR Absorption Frequency: Delocalization
1.7K
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or bond. This phenomenon is common in systems with conjugated bonds—structures where alternating single and double bonds allow π-electrons to move freely across the network. The movement of electrons stabilizes the molecule and can affect various chemical properties, including vibrational frequencies observed in IR spectroscopy.
In IR...
In IR...
1.7K


