合成米卡斯中的二维到三维磁性
José Luis Rosas-Huerta1, Jonas Wolber1,2, Claire Minaud1
1Unité de Catalyse et Chimie du Solide (UCCS) - Université de Lille - Centrale Lille, Université Artois, ENSCL, UMR CNRS 8181, Lille, F-59000, France.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|September 20, 2024
概括
基于Fe的米卡表现出双重磁性行为,旋转眼镜或铁磁铁. 这项研究揭示了四面体中的内层铁触发了3D磁转换,解决了这些磁性矿物质的二元性.
科学领域:
- 固态化学 固态化学
- 材料科学 材料科学 材料科学
- 磁力学 磁力学 是一种
背景情况:
- 基于铁的 mica 矿物质具有双重磁性,可以作为旋转玻璃或分层的铁磁体.
- 这种磁性双重性的根本原因尚不清楚,这在理解这些材料方面构成了重大挑战.
研究的目的:
- 为了阐明基于Fe的矿物质中对立的磁性基态的原因.
- 研究影响合成米卡中的磁转换的结构和电子因素.
主要方法:
- 合成和表征KFe3[MGe3]O10X2米卡斯 (M=Fe,Ga;X=OH-,F-).这些米卡斯的合成和表征.
- 中子衍射以确定磁结构和过渡.
- 密度函数理论与哈巴德U (DFT+U) 对磁交换合的计算.
主要成果:
- 在KFe3[FeGe3]O10(OH) 2.2.中观察到一个2D到3D的磁性过渡.
- 在相应的化物类似物和Ga替代样品中检测到最小的磁性顺序.
- 铁在内层四面体中的存在被确定为驱动3D磁性过渡的关键因素.
结论:
- 合成中的内层铁对于实现3D磁性转换至关重要.
- 这种内层铁防止了八面体层之间的磁,解决了长期存在的Fe-based mica磁性的二元性.
相关概念视频
Potential Due to a Magnetized Object
265
Magnetic dipoles in magnetic materials are aligned when placed under an external magnetic field. For paramagnets and ferromagnets, dipole alignment occurs in the direction of the magnetic field. However, the dipoles align opposite to the field in the case of diamagnets. This state of magnetic polarization due to the external field is called magnetization. Magnetization is defined as the dipole moment per unit volume. It plays a similar role to polarization in electrostatics.
The vector...
The vector...
265
Diamagnetism
2.4K
Materials consisting of paired electrons have zero net magnetic moments. However, when these materials are placed under an external magnetic field, the moments opposite to the field are induced. Such materials are called diamagnets. Diamagnetism is the response of the diamagnets when placed in an external magnetic field.
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
Diamagnetism was discovered by Anton Brugmans in 1778 when he observed that bismuth gets repelled by magnetic fields, thus theorizing that diamagnets get repelled by magnets....
2.4K
Ferromagnetism
2.4K
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
2.4K
Magnetic Resonance Imaging
5.0K
Magnetic resonance imaging (MRI) is a noninvasive medical imaging technique based on a phenomenon of nuclear physics discovered in the 1930s, in which matter exposed to magnetic fields and radio waves was found to emit radio signals. In 1970, a physician and researcher named Raymond Damadian noticed that malignant (cancerous) tissue gave off different signals than normal body tissue. He applied for a patent for the first MRI scanning device in clinical use by the early 1980s. The early MRI...
5.0K
Magnetic Susceptibility and Permeability
998
In linear magnetic materials, like paramagnets and diamagnets, magnetization is proportional to the magnetic field intensity. The constant of proportionality, a dimensionless number, is called magnetic susceptibility. The value of the susceptibility depends on the type of material.
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
When diamagnetic materials are placed under an external magnetic field, the moments opposite to the field are induced. Hence, the susceptibility for diamagnets has a minimal negative value of 10-5–10-6. Since...
998
Paramagnetism
2.5K
Paramagnets are materials with unpaired electrons that possess a finite magnetic moment. In the absence of a magnetic field, these moments are randomly oriented, and thus the net moment is zero. Under an external field, a torque acting on the moments tends to align them along the field's direction. However, the random thermal motion of electrons produces a torque opposite to the external field and tries to disorient the moments. These two competing effects align only a few moments along the...
2.5K


