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Updated: Jun 12, 2025

Regioselective O-Glycosylation of Nucleosides via the Temporary 2',3'-Diol Protection by a Boronic Ester for the Synthesis of Disaccharide Nucleosides
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在甲基化物中对基基的迁移:配置和构造决定了动力学

Leon M Friedrich1, Clemens Lütjohann1, Bernd Hartke2

  • 1Otto Diels Institute of Organic Chemistry, Christiana Albertina University of Kiel, Otto-Hahn-Platz 3-4, 24118, Kiel, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany)
|September 21, 2024
PubMed
概括

在帕拉尼特罗 (PNP) 甘酸乙烯中,亚利尔迁移在 cis 导向的基基团之间更快. 这项研究揭示了迁移率与糖形态能量障碍相关,影响碳水化合物合成.

关键词:
阿里尔迁移的迁移碳水化合物 碳水化合物计算化学是一种计算化学.运动学 运动学核磁共振光谱法 (NMR) 是一种光谱法.

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