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相关概念视频

Solvating Effects02:12

Solvating Effects

7.4K
An understanding of the solvating effect helps rationalize the relation between solvation and acidity of the compound. In addition, this also explains the relative stability of conjugate bases for compounds with different pKa values. This lesson details, in-depth, the principle of solvating effects. The strength of an acid and the stability of its corresponding conjugate base are determined using pKa values. This observed relationship is a consequence of solvation, which is the interaction...
7.4K
Ionic Bonds00:42

Ionic Bonds

118.1K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
118.1K
Electrolyte and Nonelectrolyte Solutions02:21

Electrolyte and Nonelectrolyte Solutions

62.4K
Substances that undergo either a physical or a chemical change in solution to yield ions that can conduct electricity are called electrolytes. If a substance yields ions in solution, that is, if the compound undergoes 100% dissociation, then the substance is a strong electrolyte. Complete dissociation is indicated by a single forward arrow. For example, water-soluble ionic compounds like sodium chloride dissociate into sodium cations and chloride anions in aqueous solution.
62.4K
Intermolecular Forces03:13

Intermolecular Forces

57.9K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
57.9K
Aqueous Solutions and Heats of Hydration02:42

Aqueous Solutions and Heats of Hydration

14.6K
Water and other polar molecules are attracted to ions. The electrostatic attraction between an ion and a molecule with a dipole is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.
When ionic compounds dissolve in water, the ions in the solid separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process...
14.6K
Ion Exchange01:17

Ion Exchange

564
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
564

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相关实验视频

Updated: Jun 12, 2025

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

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弱溶解以为基础的电解质构建离子衍生的固体电解质接口在石墨阳极向高稳定的离子电池.

Qilin Feng1, Jiangmin Jiang1,2, Shuang Li1

  • 1Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments, School of Materials Science and Physics, China University of Mining and Technology, Xuzhou, 221116, China.

Small (Weinheim an der Bergstrasse, Germany)
|September 23, 2024
PubMed
概括

开发用于离子电池 (PIB) 的先进电解质是关键. 一种新的弱溶解电解质在石墨阳极上创建了一个强大的,富含无机的固体电解质接口 (SEI),提高电池性能和稳定性.

关键词:
石墨阳极是一种石墨阳极.有机-无机混合 SEI 公司.离子电池的电池是离子电池.溶解结构是一种溶解结构.弱溶解电解质的电解质的溶解能力较低.

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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
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Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
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科学领域:

  • 材料科学 材料科学 材料科学
  • 电化学 电化学 电化学
  • 储能 储能 储能 储能 储能 储能

背景情况:

  • 石墨是离子电池 (PIB) 的一个有希望的,低成本的阳极.
  • 一个稳定的有机丰富的固体电解质接口 (SEI) 对于 PIB 的表现至关重要.
  • 传统的电解质形成厚厚的有机SEI,阻碍离子间隔和电池效率.

研究的目的:

  • 为 PIB 中的石墨阳极设计一个优质的 SEI 层.
  • 提高PIBs的电化学性能和循环稳定性.
  • 探索电解质溶解结构对SEI形成的影响.

主要方法:

  • 使用弱溶解电解质来修改离子溶解结构.
  • 通过电化学分析研究了SEI的组成和形态.
  • 组装并测试了一个全离子电池 (PTCDA//石墨) 设备.

主要成果:

  • 低溶解电解质促进了形成一个统一的,富含无机物,具有增强机械性能的SEI.
  • 在石墨阳极实现了269 mAh g-1的高可逆容量.
  • 在完整的电池中证明了稳定的金属涂层/脱落 (96.5%) 和卓越的循环稳定性.

结论:

  • 优化离子溶解膜结构是高性能PIB的可行策略.
  • 低溶解电解质可以形成强大的SEI,这对于先进的电池技术至关重要.
  • 这种方法为开发下一代储能解决方案提供了一个有希望的途径.