工程多元件3DOM FeVCrO催化剂具有高氧移动性,用于氧化脱1-丁烯与CO2的氧化脱
Xiaoshuai Gao1,2, Weigao Han2, Fang Dong2
1National & Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials, Henan University, Kaifeng 475004, China. qiuyeli@henu.edu.cn.
Nanoscale
|September 23, 2024
概括
开发新的基于Fe的催化剂显著增强了利用二氧化碳对1-丁烯的氧化脱. 多组件催化剂提高了晶格氧气的流动性,促进了1-丁烯转化和1,3-丁烯产量.
科学领域:
- 催化剂是一种催化剂.
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 氧化脱 (ODH) 的1-丁到1,3-丁 (BD) 使用二氧化碳是一个关键的工业过程.
- 基于Fe的催化剂是有希望的,但由于晶格氧气流动性不佳而受到限制.
- 改善晶格氧气流动性对于增强催化活性至关重要.
研究的目的:
- 开发新的基于Fe的3D有序巨孔 (3DOM) 催化剂,以改善晶格氧气流动性.
- 使用CO2优化1-丁烯的氧化脱.
- 为了研究多组件元件对催化剂性能的影响.
主要方法:
- 使用PMMA模板方法制备3DOM铁基催化剂 (FeVAlO,FeCrAlO,FeVCrAlO).使用PMMA模板方法制备3DOM铁基催化剂 (FeVAlO,FeCrAlO,FeVCrAlO).
- 对1-丁烯转化和BD产量的催化活性测试.
- 使用现场DRIFTS进行表征,以研究水条件下的反应机制.
主要成果:
- 多组件FeVCrAlO催化剂表现出最高活性,实现了88.3%的1-丁烯转化和27.5%的BD产量.
- 引入V和Cr促进了γ-Fe2O3阶段,形成了活跃的V5+和Cr6+物种.
- 在多元组件催化剂中,格子氧气流动性得到了显著的增强.
- 在反应条件下,二氧化碳以HCO3的形式被利用,改善了二氧化碳的利用率并改变了反应途径.
结论:
- 多组件3DOM基于Fe的催化剂有效地增强了1-丁烯与CO2的氧化脱.
- 改善格子氧气流动性和活性位点的形成是提高性能的关键.
- 该研究提供了关于二氧化碳利用机制和在水存在时的反应途径的见解.
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