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相关概念视频

Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Ionic Crystal Structures02:42

Ionic Crystal Structures

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Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
14.2K
Ionic Bonding and Electron Transfer02:48

Ionic Bonding and Electron Transfer

41.3K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions. 
41.3K
Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
23.5K
Ionic Strength: Overview01:12

Ionic Strength: Overview

1.3K
The ionic strength of a solution is a quantitative way of expressing the total electrolyte concentration of a solution. This concept was first introduced in 1921 by two American physical chemists, Gilbert N. Lewis and Merle Randall, while describing the activity coefficient of strong electrolytes. During the calculation of ionic strength (I or μ), all the cations and anions are considered. However, the concentration (c) of an ion with a greater charge number (z) has a greater contribution...
1.3K
Ionic Bonds00:42

Ionic Bonds

118.1K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
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调整集体离子运动使固态化物电解质的超离子导电性成为可能.

Zhantao Liu1, Po-Hsiu Chien2, Shuo Wang3

  • 1George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, USA.

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概括

研究人员发现,离子运动驱动Li3MX6固体电解质中的离子过渡. 这一发现使得能够设计出具有改善离子导电性的新材料,用于先进的固态离子电池.

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科学领域:

  • 材料科学 材料科学 材料科学
  • 固态化学 固态化学
  • 电化学 电化学 电化学

背景情况:

  • 3MX6化物是固态离子电池的有希望的固体电解质.
  • 它们比硫化物具有更好的化学和电化学稳定性,但离子导电性较低.
  • 了解它们的离子运输机制对于材料设计至关重要.

研究的目的:

  • 为了阐明Li3MX6材料中超离子转换的机制.
  • 开发一种合理的设计策略,以提高室温离子导电性.
  • 为高性能电池发现新的超声波导体.

主要方法:

  • 同步射线X射线和中子散射的特征.
  • 一开始的分子动力学模拟.
  • 合理设计和合成化物固体电解质.

主要成果:

  • 在Li3YCl6中超离子过渡是由集体离子运动触发的.
  • 一个合理的设计策略成功降低了过渡温度.
  • 合成的Li3YCl4.5Br1.5和Li3GdCl3Br3获得了较高的室温导电性 (6.1和11 mS cm−1).

结论:

  • 集体离子运动是Li3MX6化物中超离子导电性的关键.
  • 这种理解有助于设计出优质固体电解质.
  • 新的化物材料显示出高性能固态电池的潜力.