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不对称的气体扩散层,以改善无PGM电极中的水管理
Tanvir Alam Arman1,2, Siddharth Komini Babu1, Mayank Sabharwal3
1Los Alamos National Laboratory, Los Alamos, NM, 87544, USA.
Heliyon
|September 24, 2024
概括
不对称的气体扩散层通过优化水资源管理来提高质子交换膜燃料电池 (PEMFC) 的性能. 这种配置可以在厚厚的,不含白金组金属的电极中增强氧气运输,从而降低了清洁运输的成本.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 质子交换膜燃料电池 (PEMFC) 是一个有前途的无碳排放能源,用于运输.
- 与组金属 (PGM) 催化剂相关的高成本阻碍了PEMFC的商业化.
- 无PGM的催化剂需要厚厚的电极,导致大规模运输损失和具有挑战性的水/氧管理.
研究的目的:
- 调查阳极和阴极气体扩散层 (GDL) 配置对PEMFCs水资源管理的影响.
- 与对称的配置相比,评估不对称的GDL配置的性能.
- 了解GDL设计如何影响水和和氧气运输.
主要方法:
- 用不同的GDL配置 (对称与非对称) 制造和测试PEMFC.
- 使用非对称的GDL,其阳极的GDL透率高于阴极的GDL.
- 使用计算建模来分析水资源管理和氧气运输动态.
主要成果:
- 不对称的GDL配置比对称的配置表现出更高的性能.
- 观察到改善的水资源管理,其特点是液态水和度较低.
- 电极内的更快的氧气运输通过计算建模得到证实.
结论:
- 不对称的GDL设计有效地提高了PEMFC的性能.
- 通过GDL配置优化水资源管理对于没有PGM的厚电极至关重要.
- 这种方法为减少PEMFC成本和提高可持续能源解决方案效率提供了一条途径.
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