使用原子力显微镜追踪张力下SIS热塑性弹性体的形态和应力分布的演变,使用原子力显微镜
Ling Gao1, Haonan Liu2, Xiaobin Liang2
1College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang, Hubei, China.
Science and technology of advanced materials
|September 24, 2024
概括
基于styrene的triblock共聚合物,称为热塑性弹性体,在张力下显示域破裂和重组. 这项研究揭示了微观结构的变化如何影响这些材料的性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 纳米技术 纳米技术
背景情况:
- 基于氨酸的ABA型triblock共聚合物是关键的热塑性弹性体 (TPE).
- 了解拉伸TPE中的微结构-属性关系对于设计坚固材料至关重要.
- 聚乙烯-异乙烯-乙) 混合物因其弹性质而受到广泛研究.
研究的目的:
- 为了研究聚乙烯-异乙烯-乙烯的变形行为,在压力下混合.
- 为了澄清在拉伸过程中微观结构和宏观性质之间的关系.
- 在变形过程中分析玻璃状领域的纳米机械变化.
主要方法:
- 基于原子力显微镜 (AFM) 的定量纳米机械映射.
- 聚合物混合物的拉力测试.
- 在拉伸过程中分析JKR Young的模量.
- 变形前后的微观结构分析.
主要成果:
- 玻璃聚烯 (PS) 域变形,导致不均的应力分布.
- 在200%的压力下启动PS域的破解.
- 在JKR的模量变化与压力-应变行为相关联.
- 在拉伸过程中存在域区分离和重组的证据.
结论:
- 这项研究阐明了压力下的基于烯的TPE的变形机制.
- 纳米机械绘制揭示了影响材料性质的关键微观结构变化.
- 这些发现有助于合理设计高强度和弹性热塑性弹性体.
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