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Updated: Jun 12, 2025

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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在铜光氧催化原子转移激素添加中研究竞争的内部和外部球电子转移途径:结束循环

Le Nhan Pham1, Angus Olding2, Curtis C Ho2

  • 1Institute for Nanoscale Science and Technology, Flinders University, South Australia, Australia.

Angewandte Chemie (International ed. in English)
|September 24, 2024
PubMed
概括

这项研究表明,铜催化剂通过内部球电子转移 (ISET) 启动原子转移激素添加. 催化剂再生,对于反应完成和酶选择性至关重要,也通过ISET在基态中发生.

关键词:
原子转移基质的加法是原子转移基质的加法铜光电氧催化剂的催化作用密度函数理论密度函数理论内部球体电子转移电子的转移外层球体电子转移电子的转移

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